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Synthesis and Screening of New Chiral Ligands for the Copper-Catalysed Enantioselective Allylic Substitution

✍ Scribed by Sandrine Ongeri; Umberto Piarulli; Maryline Roux; Chiara Monti; Cesare Gennari

Publisher: John Wiley and Sons
Year: 2002
Tongue: German
Weight: 129 KB
Volume: 85
Category: Article
ISSN: 0018-019X
DOI: 10.1002/1522-2675(200210)85:10<3388::aid-hlca3388>3.0.co;2-i

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## Abstract magnified image Unsymmetrically 3,3′‐substituted axially chiral bis(tetrahydroisoquinoline) __N,N′‐__dioxides can be prepared in just three steps. They exhibit unique catalytic activity (turnover frequency, enantioselectivity, substrate scope) in the asymmetric allylation of aromatic a