𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Enantioselective Palladium Catalyzed Allylic Substitution with New Chiral Pyridine-Phosphine Ligands.

✍ Scribed by J.-M. BRUNEL; T. CONSTANTIEUX; A. LABANDE; F. LUBATTI; G. BUONO


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis


The catalytic properties of palladium complexes, formed in situ from ( PdCl(allyl))2 and chiral pyridine-phosphine ligands, in the allylic alkylation of (I) are investigated.


πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: New Chiral Phosphin
✍ Myung-Jong Jin; Jung-Ae Jung; Sang-Han Kim πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-