Synthesis and crystal structure of a novel two-dimensional network complex [Mn(O2CCH2Cl)2(phen)]n
β Scribed by Jun Li; Jinhua Zhang; Aizhi Wu; Yun Xi; Hui Guo; Fengxing Zhang
- Publisher
- SP Science China Press
- Year
- 2005
- Tongue
- English
- Weight
- 203 KB
- Volume
- 48
- Category
- Article
- ISSN
- 1674-7291
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π SIMILAR VOLUMES
The crystal and molecular structures of [Mn(phen)-(OHz)C13] (1) and [Mn(acac)2(OHE)/]C104"2H20 (2) were determined. A comparison is made of the Jahn-Teller distortion in these compounds with those observed in other manganese(III) complexes with monodentate axial ligands.
A novel coordination polymer, [Mn(PDC)H 2 O] n (1) (H 2 PDCοΌpyridine-2,3-dicarboxylic acid), has been hydrothermally synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. X-ray single crystal structural analyses revealed that two-dimensional frameworks were fo