Synthesis and X-Ray Crystal Structure of Two Novel Complexes: [MII(phen)3]2V4O12·phen·22H2O(MII=Co, Ni;phen=phenanthroline)
✍ Scribed by L’udmila Žúrková; Renáta Kucsera; Róbert Gyepes; Michal Sivák
- Publisher
- Springer Vienna
- Year
- 2003
- Tongue
- English
- Weight
- 344 KB
- Volume
- 134
- Category
- Article
- ISSN
- 0026-9247
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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê