Synthesis and Crystal Structure of [Cu2(H2O)2(phen)2(OH)2][Cu2(phen)2(OH)2(CO3)2] · 10 H2O with phen = 1,10-phenanthroline
✍ Scribed by Yue-Qing Zheng; Jian-Li Lin; Jie Sun
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 132 KB
- Volume
- 627
- Category
- Article
- ISSN
- 0372-7874
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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê
The reaction of CuCl 2 ´2 H 2 O, 1,10-phenanthroline (phen), suberic acid and Na 2 CO 3 in a CH 3 CN±H 2 O solution yielded blue needle-like crystals of [Cu 2 (phen) 2 (C 8 H 12 O 4 ) 2 ] 3 H 2 O. The crystal structure (monoclinic, P2 1 /n, a = 10.756(2) A Ê , b = 9.790(2) A Ê , c = 18.593(4) A Ê ,
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
The title compound [Cu 2 (phen) 2 (C 9 H 14 O 4 ) 2 ] 6 H 2 O was prepared by the reaction of CuCl 2 ´2 H 2 O, 1,10phenanthroline (phen), azelaic acid and Na 2 CO 3 in a CH 3 OH/H 2 O solution. The crystal structure (monoclinic, C2/c (no. 15), a = 22.346(3), b = 11.862(1), c = 17.989(3) A Ê , b = 91