Synthesis and Crystal Structure of [La(phen)2(H2O)2(NO3)2]NO3 · 2(phen)(H2O) with phen = 1,10-phenanthroline
✍ Scribed by Yue-Qing Zheng; Lin-Xia Zhou; Jian-Li Lin; Sun-Wei Zhang
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- German
- Weight
- 103 KB
- Volume
- 626
- Category
- Article
- ISSN
- 0372-7874
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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê
The reaction of CuCl 2 ´2 H 2 O, 1,10-phenanthroline (phen), suberic acid and Na 2 CO 3 in a CH 3 CN±H 2 O solution yielded blue needle-like crystals of [Cu 2 (phen) 2 (C 8 H 12 O 4 ) 2 ] 3 H 2 O. The crystal structure (monoclinic, P2 1 /n, a = 10.756(2) A Ê , b = 9.790(2) A Ê , c = 18.593(4) A Ê ,
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