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Copper(II) complexes of heptanedioic acid (hdaH2) and octanedioic acid (odaH2) : X-ray crystal structures OF [Cu(η2-hda)(phen)2]·11.73H2O and [Cu(η2-oda)(phen)2]·12H2O (phen = 1,10-Phenanthroline)

✍ Scribed by Malachy McCann; James F. Cronin; Michael Devereux; George Ferguson

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
781 KB
Volume
14
Category
Article
ISSN
0277-5387

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Synthesis and Crystal Structure of a Nov
Synthesis and Crystal Structure of a Novel Dinuclear Copper(II) Complex, [Cu2(phen)2(H2O)2(OH)2](HCO3)2 · 6 H2O with phen = 1,10-phenanthroline
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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê

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A Novel Dinuclear Copper(II) Complex Molecule: Synthesis and Crystal Structure of Cu2(phen)2(H2O)2(C5H6O4)2 with phen = 1,10-phenanthroline
✍ Yue-Qing Zheng; Jie Sun; Jian-Li Lin 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 112 KB 👁 2 views

Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,