Synthesis and Crystal Structure of Two-dimensional Network Supramolecular Complex [Cu(dafo)2 (H2O)2] (ClO4)2
โ Scribed by Ai-Ping Gu; Rong-Lan Zhang; Gai Zhang; Jian-She Zhao; Shui-Yang He; Jian-Min Dou; Da-Qi Wang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 321 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0256-7660
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Roject supported by the Foundation of Key Laboratory of Orgiuuc Syntheses of Jiangsu Province (No. K99106).
Synthesis, spectroscopy, and crystal structures of [Cu(ca 2 en) 2 ]ClO 4 (1) and [Cu(ca 2 en)(PPh 3 ) 2 ]ClO 4 (2) (ca 2 en N,N'-bis(trans-cinnamaldehyde)ethylenediimine) are reported. Compound 1 crystallizes in the orthorhombic space group Pbca, with a 12.5647( ), b 21.8203(11), c 27.992(2) รค, V 76
Single crystals of Lu(ClO 4 ) 3 ยด3 H 2 O were obtained by slow dehydration of Lu(ClO 4 ) 3 ยด6 H 2 O at 140 ยฐC under flowing argon. The compound crystallizes in the triclinic crystal system (P1, Z = 2, a = 750.3(1), b = 838.4(1), c = 1054.6(2) pm, a = 79.77(2)ยฐ, b = 79.18(2), c = 63.83(2), R all = 0.