Crystal structure, thermal analysis and theoretical calculation of a one-dimensional chain complex [zn(dafo)2(H2O)2](NO3)2
β Scribed by Rong-Lan Zhang; Jian-She Zhao; Xin Gao; Qi-Zhen Shi; Shui-Yang He
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 361 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0256-7660
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## Abstract A oneβdimensional polymeric pyridinium chlorocuprate (HPy)~2~[Cu~3~Cl~8~(H~2~O)~2~], an intermediate between (HPy)CuCl~3~ and CuCl~2~Β·2H~2~O, has been synthesized and characterized by Xβray analysis [monoclinic, __P__2~1~/__c__, __a__ = 7.8950(10), __b__ = 14.144(2), __c__ = 9.921(10) Γ
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 Β΄6 H 2 O were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Γ