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Mononuclear manganese(III) aquo complexes. Crystal and molecular structures of [Mn(phen)(OH2)Cl3] and [Mn(acac)2-(OH2)2]ClO4·2H2O (acacH = acetylacetone, phen = 1,10-phenanthroline)

✍ Scribed by Ganti Swarnabala; K. Rajender Reddy; Jyotsna Tirunagar; Melath V. Rajasekharan


Publisher
Springer
Year
1994
Tongue
English
Weight
321 KB
Volume
19
Category
Article
ISSN
0340-4285

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✦ Synopsis


The crystal and molecular structures of [Mn(phen)-(OHz)C13] (1) and [Mn(acac)2(OHE)/]C104"2H20 (2) were determined. A comparison is made of the Jahn-Teller distortion in these compounds with those observed in other manganese(III) complexes with monodentate axial ligands.


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✍ Yue-Qing Zheng; Jie Sun; Jian-Li Lin 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 91 KB 👁 2 views

Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê