The vIbrational structure in the laser-induced fluorescence excitation spectrum of the fust excited TT\* .-n transition of thiophogene, seeded in a supersonic beam of argon, is reported. Hot bands are identified empirically by variation of beam temperature, and vibronic assignments are adjusted as r
Supersonic expansion cooling of electronically excited OH radicals
โ Scribed by A.T. Droege; P.C. Engelking
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 252 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
DKOEGE and P.C. EirfGELKING Supcr.ur~x nuzzle woiing c~fcxcitcd-srrlre molsculw radicals produced in a corona discharge is demonstuted and in-\ck:i;.~tcd using hydro\j I rJdlc&. Ror~rional rcmperatures of I1 _ + 2 I; and tibrational temperatures of 3400 + 300 K are 1ypk-.dI? obux\rd in rhc 011 A 'Z+ SIJIC. I_ Inrroduction .-\ number c,F techniques IX+? he used to prodllcc ~~~s-pk~se r.idicak. including pyrolysis. reactions with -_ IlldJSlJhkS. 9IOIll abstractio11.
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