The laser-induced fluorescence spectrum of gas-phase PHI cooled in a supersonic jet has been observed in the range 490-550 nm. A rotational analysis was carried out for the (0, 0, 0)-(0, 0, 0), (0, 1, 0)-(0, 0,O) and (0,2,0)-(O, O, 0) bands of the A 'A,-X ZBI electronic transition of PHr. About 220
Laser-induced fluorescence excitation spectrum of thiophosgene cooled by supersonic expansion
โ Scribed by R. Vasudev; Y. Hirata; E.C. Lim; W.M. McClain
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 347 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The vIbrational structure in the laser-induced fluorescence excitation spectrum of the fust excited TT* .-n transition of thiophogene, seeded in a supersonic beam of argon, is reported. Hot bands are identified empirically by variation of beam temperature, and vibronic assignments are adjusted as required.
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The high resolution, rotationally resolved laser induced fluorescence spectra for the A2A1 left and right arrow X2E transitions of CF3O and CF3S were recorded. In addition to the origins, the symmetric vibrational band 301 and the nontotally symmetric bands 501 and 601 were analyzed for CF3O, while
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