The laser-induced fluorescence spectrum of gas-phase PHI cooled in a supersonic jet has been observed in the range 490-550 nm. A rotational analysis was carried out for the (0, 0, 0)-(0, 0, 0), (0, 1, 0)-(0, 0,O) and (0,2,0)-(O, O, 0) bands of the A 'A,-X ZBI electronic transition of PHr. About 220
Laser-induced fluorescence of the calcium dimer in supersonic jet: The red spectrum of Ca2
โ Scribed by V.E. Bondybey; J.H. English
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 487 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
cilz is produced by pulsed YAG laser vaporization of calcium metal and cooling of the vapor in a pulsed supersonic jet. The Ca2 spectra are studied by time-resolved laser-induced fluorescence. The esistence of a low-lying A 'xi state with voo = 14517 f 2 cm-' and wc = 131 cm-t is confirmed_ The spect~oscop)i and electronic structure of G2 are discussed.
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A laser-induced-fluorescence (LIF) investigation of the jet-cooled dimer of the aromatic molecule N-ethylcarbazole is presented. The dimer behaves essentially as a perturbed monomer. The origin is shifted bathochromically some 606.8 cm-' relative to that of the monomer, and this can be explained in
We report the first successful demonstration of a LIF study performed on small molecular ions in a jet expansion produced by resonantly enhanced multiphoton ionization. The study involves the 2 + 1 multiphoton ionization via the B 'X + state ofjet-cooled CO molecules. Sufftcient downstream densities