✦ LIBER ✦

Laser-induced fluorescence excitation spectra of jet-cooled chrysene

✍ Scribed by Haiping Yu; Evelyn Joslin; David Phillips

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 669 KB
Volume: 203
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85302-5

No coin nor oath required. For personal study only.

✦ Synopsis

Tbe laser-induced fluorescence excitation spectmm of the S,+& transition of jet-cooled chrysene is reported for the first time in the range 26500-29800 cm-l, together with experimentally recorded rovibronic band contours of six of the more active transitions in the spectrum. A preliminary analysis of vibronic features of the first excited singlet state is given, based primarily on ground state vibrational assignments together with comparison of the fluorescence spectra of other jet-cooled polycyclic benzenoid hydrocarbons. An intense progression in the out-of-plane buttefiyingmotion is observed. The weak transition at 26595 cm-' is assigned to the origin band in this molecule, which is shifted about 1000 cm-' to the red of the S, origin reported by others.

📜 SIMILAR VOLUMES

Laser-induced fluorescence spectra of je

Laser-induced fluorescence spectra of jet cooled p-chlorobenzyl radical

✍ Masaru Fukushima; Kinichi Obi 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 527 KB

We have generated the p-chlorobenzyl radical in supersonic free expansion, and measured the laser-induced fluorescence (LIF) excitation spectra and LIF dispersed spectra from single vibronic levels (SVL). Based on an analysis of the dispersed spectra, we find the two band origins, spaced only 94 cm-

Fluorescence excitation spectra of jet-c

Fluorescence excitation spectra of jet-cooled amino-phthalimides

✍ M. Asimov; N.P. Ernsting 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 146 KB

Rotational Analyses of the Laser Induced

Rotational Analyses of the Laser Induced Fluorescence Excitation Spectra of Jet-Cooled CF3O and CF3S

✍ M.-C. Yang; J.M. Williamson; Terry A. Miller 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 358 KB

The high resolution, rotationally resolved laser induced fluorescence spectra for the A2A1 left and right arrow X2E transitions of CF3O and CF3S were recorded. In addition to the origins, the symmetric vibrational band 301 and the nontotally symmetric bands 501 and 601 were analyzed for CF3O, while

Laser-induced fluorescence of jet-cooled

Laser-induced fluorescence of jet-cooled 4-aminobenzonitrile

✍ Elizabeth M. Gibson; Anita C. Jones; David Phillips 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 362 KB

Fluorescence excitation and dispersed fluorescence spectra of jet-cooled 4-aminobenzonitrile are reported. These spectra are free from the low frequency transitions which complicate the spectra of the related molecule 4-N,Ndimethylaminobenzonitrile, and can be assigned in terms of fundamentals chara

Fluorescence excitation spectrum of jet-

Fluorescence excitation spectrum of jet-cooled dihydroanthracene

✍ Tapas Chakraborty; Mihir Chowdhury 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 347 KB

The lowest excited singlet site of 9,10-dihydroanthracene has been studied by supersonic-jet laser spectroscopy. The spectrum consists of a number of prominent low-frequency vibronic bands near the O-O band followed by a structureless continuum. The low-frequency vibronic bands are nicely fitted wit

Laser-induced fluorescence spectra of fr

Laser-induced fluorescence spectra of free-jet cooled organic free radicals. Vinoxy, cyclopentadienyl, and benzyl

✍ M. Heaven; L. Dimauro; Terry A. Miller 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 470 KB