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Laser-induced fluorescence spectra of jet cooled p-chlorobenzyl radical

✍ Scribed by Masaru Fukushima; Kinichi Obi

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 527 KB
Volume: 248
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)01333-4

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✦ Synopsis

We have generated the p-chlorobenzyl radical in supersonic free expansion, and measured the laser-induced fluorescence (LIF) excitation spectra and LIF dispersed spectra from single vibronic levels (SVL). Based on an analysis of the dispersed spectra, we find the two band origins, spaced only 94 cm-i apart, of the D] 1 2A 2-and D 2 2 2Bj-Do 1 2B I transitions in the excitation spectrum. We also observe interstate level mixing between the 6b and 12 vibronic levels of the D 2 and D l states, respectively, in the excitation spectrum, and the vibronic coupling is analyzed using a simple model within the Born-Oppenheimer (B-O) approximation.

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