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Lifetimes of electronically excited NO2 in a collision-free differentially pumped supersonic molecular beam

✍ Scribed by Ori Chesnovsky; Aviv Amirav

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 494 KB
Volume: 109
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85603-1

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✦ Synopsis

The lifetimes of rotationally cooled NO, were measured in the spectral region 5710-5960 A in a differentially pumped collision-free supersonic molecular beam. Lifetime values (rotationally independent) between 75 and 260 ps were obtained.

Over narrow spectral regions, the product of the fluorescence aznpiitude and the lifetime squared is vibrationally independent, as prcdicrcd by theory.

' A Batsheva de Rothschild Fellow.

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