The 2B1(K′ = 1)-X̃2A1(K″ = 0) subbands of NO2 found in the excitation spectrum using a supersonic molecular beam
✍ Scribed by Nobuo Sugimoto; Sanzo Takezawa
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 244 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
-0) subbands at 4641 and 445.6 nm are idenlified in the fluorescence exciralion specua or NO, roIa1ionally cooled in a supersonic jet. The origins of both bands agree well with a calculakm based on rhe theory of Ihe Renner-Teller effect. and the Mbrarional signmenu ui = 14 and 16 are given IO the upper levels, respextively.
📜 SIMILAR VOLUMES
The rotational structure of the 2B, state of NO\* is analyzed by means of the time-gated escitation spectrum. monitored at the 3v2 band. The band origins ~0 and the rotational constants are evaluated from the observed data: vo = 20204.86 cm-t.
The rotational structure of the \*Br(K' = 1) sub-band of NO2 was, for the fust time, analyzed in the thne-gated escitation spectrum monitored at the 31~2 fluorescence band. The band origin, ho = 2 15019 cm-', and rotational constant, z' = 0.373 cm-' , were obtained. The observed sub-band was vibrati