The rotational structure of the 2B, state of NO\* is analyzed by means of the time-gated escitation spectrum. monitored at the 3v2 band. The band origins ~0 and the rotational constants are evaluated from the observed data: vo = 20204.86 cm-t.
Degenerate four-wave mixing thermometry on the 2B1(k″ = 0)–2A1(k′ = 1) Douglas–Huber band of NO2
✍ Scribed by L. De Dominicis; R. Fantoni
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 173 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0377-0486
- DOI
- 10.1002/jrs.930
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📜 SIMILAR VOLUMES
The rotational structure of the \*Br(K' = 1) sub-band of NO2 was, for the fust time, analyzed in the thne-gated escitation spectrum monitored at the 31~2 fluorescence band. The band origin, ho = 2 15019 cm-', and rotational constant, z' = 0.373 cm-' , were obtained. The observed sub-band was vibrati
-0) subbands at 4641 and 445.6 nm are idenlified in the fluorescence exciralion specua or NO, roIa1ionally cooled in a supersonic jet. The origins of both bands agree well with a calculakm based on rhe theory of Ihe Renner-Teller effect. and the Mbrarional signmenu ui = 14 and 16 are given IO the up