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Rotational analysis of the 2B1(K′ = 1) -2A1 (K″ = 0) sub-band of NO2 at 464.9 nm in the time-gated excitation spectrum

✍ Scribed by Nobuo Sugimoto; Nobuo Takeuchi; Sanzo Takesawa

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
298 KB
Volume
99
Category
Article
ISSN
0009-2614

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✦ Synopsis

The rotational structure of the *Br(K' = 1) sub-band of NO2 was, for the fust time, analyzed in the thne-gated escitation spectrum monitored at the 31~2 fluorescence band. The band origin, ho = 2 15019 cm-', and rotational constant, z' = 0.373 cm-' , were obtained. The observed sub-band was vibrationally identitied to be (uU;* K') = (16,l) witb the linear notation. Also a vibrational assignment of the transitions. the rotational identiiication of which was reported by Senum and Schwartz is proposed.

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Rotational analysis of the 2B1 (K′ = 0)←
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✍ Sanzo Takezawa; Nobuo Sugimoto; Nobuo Takeuchi 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 269 KB

The rotational structure of the 2B, state of NO\* is analyzed by means of the time-gated escitation spectrum. monitored at the 3v2 band. The band origins ~0 and the rotational constants are evaluated from the observed data: vo = 20204.86 cm-t.

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✍ Nobuo Sugimoto; Sanzo Takezawa 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 244 KB

-0) subbands at 4641 and 445.6 nm are idenlified in the fluorescence exciralion specua or NO, roIa1ionally cooled in a supersonic jet. The origins of both bands agree well with a calculakm based on rhe theory of Ihe Renner-Teller effect. and the Mbrarional signmenu ui = 14 and 16 are given IO the up