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The EPR spectrum of vibrationally excited OH radicals

โœ Scribed by P.N. Clough; A.H. Curran; B.A. Thrush

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
299 KB
Volume
7
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Vibrationally excited hydroxyl radicals (v = 1 to 4) produced by Cbe reaction of hydro&xz atoms w&Et ozone have been detected by gae phase electron paramngnetic resmce ia the J = 312 level of i&e %I~,c~ AZ&?.

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The vibration-rotation bands (hleinel bands) of the ground electronic state of OH have been observed in the chemiluminescent gas phase reactions of ozone with ethylene, propylene, I-butene, cis-2-butene and tetramethytethylene at total pressures of about 3 torr at room temperature. The emitting spec