✦ LIBER ✦

Production of vibrationally excited OH in chemiluminescent ozone-olefin reactions

✍ Scribed by B.J. Finlayson; J.N. Pitts Jr.; H. Akimoto

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 331 KB
Volume: 12
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)90016-4

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✦ Synopsis

The vibration-rotation bands (hleinel bands) of the ground electronic state of OH have been observed in the chemiluminescent gas phase reactions of ozone with ethylene, propylene, I-butene, cis-2-butene and tetramethytethylene at total pressures of about 3 torr at room temperature. The emitting species in the reactions of the I-o,lefms with ozone have been tentatively identified as HCHO('Az) and electronically excited o4iurbonyl compounds.

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