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Infrared chemiluminescence from vibrationally excited no+: product branching in the N+ + O2 ion-molecule reaction

✍ Scribed by Mark A. Smith; Veronica M. Bierbaum; Stephen R. Leone


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
568 KB
Volume
94
Category
Article
ISSN
0009-2614

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✦ Synopsis


11i Chcrnisf~~. L'ln%ws& of Colorado_ Boulder. Colorado SO309. USA 'ihr;ltional ctl~mi1unlinesccnc-c is dercctcd from the reaction N*("P) i-Oz(S"Q in a flowing -after~lo\v. The atomtrnnsfcr product. NO+(X ' 1.+. u). displays a bimodal vibrationaldistribution spanning the nnge v = l-14. Excited N('D) is found to be the nmjor charge-transfer Product by obserwtion of its further reaction with 02 to produce NO(X'n. v= I-.?\ 1 L,.