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Structure of chloro(α,β,γ,δ-tetraphenylporphinato)manganese(III) toluene solvate

✍ Scribed by Armstrong, R. S. ;Foran, G. J. ;Hambley, T. W.


Book ID
114509671
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
346 KB
Volume
49
Category
Article
ISSN
0108-2701

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In the crystal structure of the title compound, [Co(C 44 H 28 N 4 )-(NO 2 )]ÁC 6 H 6 , the Co III atom has a distorted square±pyramidal coordination, with the nitro ligand at the apical position. The CoÐN(nitro) bond distance is 1.880 (3) A Ê .

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In the crystal structure of the title compound, [Co(NO 2 )-(C 44 H 28 N 4 )(H 2 O)]ÁCH 2 Cl 2 , the Co III atom has a distorted octahedral coordination, with the water molecule trans to the nitro ligand. The CoÐN(nitro) and CoÐO(aqua) bond distances are 1.863 (8) and 2.114 (8) A Ê , respectively. Th