Chloro(tetraphenylchlorin)manganese(III) has been synthesized and characterized. Vkible and infrared spectra of the complex have been measured and band assignments made. The Mn(III) --, Mn(II) reduction potential, &It = -0.15 v (vs SCE), of the complex in dimethylformamide was determined polarograph
Structure of chloro(α,β,γ,δ-tetraphenylporphinato)manganese(III) toluene solvate
✍ Scribed by Armstrong, R. S. ;Foran, G. J. ;Hambley, T. W.
- Book ID
- 114509671
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 346 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the crystal structure of the title compound, [Co(C 44 H 28 N 4 )-(NO 2 )]ÁC 6 H 6 , the Co III atom has a distorted square±pyramidal coordination, with the nitro ligand at the apical position. The CoÐN(nitro) bond distance is 1.880 (3) A Ê .
In the crystal structure of the title compound, [Co(NO 2 )-(C 44 H 28 N 4 )(H 2 O)]ÁCH 2 Cl 2 , the Co III atom has a distorted octahedral coordination, with the water molecule trans to the nitro ligand. The CoÐN(nitro) and CoÐO(aqua) bond distances are 1.863 (8) and 2.114 (8) A Ê , respectively. Th