Chloro-α,β,γ,δ-tetraphenylporphinatopyridinecobalt(III)
✍ Scribed by Sakurai, T. ;Yamamoto, K. ;Seino, N. ;Katsuta, M.
- Book ID
- 117859787
- Publisher
- International Union of Crystallography
- Year
- 1975
- Weight
- 436 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0567-7408
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Chloro(tetraphenylchlorin)manganese(III) has been synthesized and characterized. Vkible and infrared spectra of the complex have been measured and band assignments made. The Mn(III) --, Mn(II) reduction potential, &It = -0.15 v (vs SCE), of the complex in dimethylformamide was determined polarograph
In the crystal structure of the title compound, [Co(NO 2 )-(C 44 H 28 N 4 )(H 2 O)]ÁCH 2 Cl 2 , the Co III atom has a distorted octahedral coordination, with the water molecule trans to the nitro ligand. The CoÐN(nitro) and CoÐO(aqua) bond distances are 1.863 (8) and 2.114 (8) A Ê , respectively. Th