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Stereospecific polymerization of butadiene with π-allyl nickel complexes containing various ligands

✍ Scribed by V.A. Yakovlev; B.A. Dolgoplosk; Ye.I. Tinyakova; O.N. Yakovleva

Book ID
118358764
Publisher
Elsevier Science
Year
1969
Weight
671 KB
Volume
11
Category
Article
ISSN
0032-3950

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Investigation of the mechanism of polymerization of butadiene by π-allylic nickel complexes
✍ Bourdauducq, P. ;Dawans, F. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 842 KB

## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio