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Disproportionation of π-allylic nickel complexes and the formation of cyclododecatriene during the stereospecific polymerization of butadiene

✍ Scribed by V. A. Yakovlev; E. I. Tinyakova; B. A. Dolgoplosk

Book ID
112481484
Publisher
Springer
Year
1968
Tongue
English
Weight
47 KB
Volume
17
Category
Article
ISSN
1573-9171

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✍ Bourdauducq, P. ;Dawans, F. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 842 KB

## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio