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Polymerization by transition metal derivatives XI. Stereospecific polymerization of butadiene in the presence of π-allyl nickel halogenoacetates

✍ Scribed by Dawans, F. ;Teyssié, Ph.

Publisher
Wiley (John Wiley & Sons)
Year
1969
Tongue
English
Weight
160 KB
Volume
7
Category
Article
ISSN
0449-2986

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Investigation of the mechanism of polyme
Investigation of the mechanism of polymerization of butadiene by π-allylic nickel complexes
✍ Bourdauducq, P. ;Dawans, F. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 842 KB

## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio