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Stereospecific polymerization of butadiene in the presence of π-allylic complexes

✍ Scribed by B.D. Babitskii; B.A. Dolgoplosk; V.A. Kormer; M.I. Lobach; Ye.I. Tinyakova; N.N. Chesnokova; V.A. Yakovlev


Book ID
118356593
Publisher
Elsevier Science
Year
1964
Weight
55 KB
Volume
6
Category
Article
ISSN
0032-3950

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✍ Bourdauducq, P. ;Dawans, F. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 842 KB

## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio