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Effect of electron donor additions on the polymerization of butadiene in the presence of π-allyl nickel catalysts

✍ Scribed by E.V. Kristal'nyi; N.V. Orekhova; Ye.V. Zabolotskaya; A.R. Gantmakher; S.S. Medvedev

Book ID
118359237
Publisher
Elsevier Science
Year
1970
Weight
321 KB
Volume
12
Category
Article
ISSN
0032-3950

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Investigation of the mechanism of polyme
Investigation of the mechanism of polymerization of butadiene by π-allylic nickel complexes
✍ Bourdauducq, P. ;Dawans, F. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 842 KB

## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio