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Polymerization of butadiene on a catalyst obtained interacting bis(π-allyl)nickel with silica

✍ Scribed by Yermakov, Yu. I. ;Grabovskii, Yu. P. ;Lazutkin, A. M.

Book ID
112686443
Publisher
Springer
Year
1974
Tongue
English
Weight
194 KB
Volume
1
Category
Article
ISSN
0133-1736

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π-Allyl nickel halide–oxygen system as a
π-Allyl nickel halide–oxygen system as a catalyst for polymerization of butadiene
✍ Matsumoto, Tsuyoshi ;Furukawa, Junji ;Morimura, Hirohisa 📂 Article 📅 1971 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 536 KB

## Abstract The π‐allyl nickel halide‐oxygen system was found to be active as catalyst for stereospecific polymerization of butadiene. The catalyst from π‐allyl nickel chloride or π‐allyl nickel bromide yields the polymer of 90% __cis__‐1,4 content with high activity, whereas the catalyst from π‐al