Stereoselective Syntheses of Optically Active Amino Acids from Menthyl Esters of α-Keto Acids 1
✍ Scribed by Matsumoto, Kazuo; Harada, Kaoru
- Book ID
- 126429093
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 408 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Simple amino acids (1) can be converted in fair to good yield into hydrazino acids (3) of like configuration by using KOCI instead of NaOCl to promote the Shestakov rearrangement of the intermediate hydantoic acids (2). It was shown fifteen years ago by Karady et al.,' and later by Custafsson,' that
Acyloxy)alkyl esters are commonly employed as prodrugs of carboxylic acid containing compounds. Several optically active (acyloxy)alkyl esters are prepared from a coupling and rearrangement reaction between optically active O-acyl-a-hydroxy acids and 3-chloroperoxybenzoic acid mediated by diisopropy