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Stable Oxoborate with Edge-Sharing BO4 Tetrahedra Synthesized under Ambient Pressure

✍ Scribed by Shifeng Jin; Gemei Cai; Wanyan Wang; Meng He; Shunchong Wang; Xiaolong Chen


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
509 KB
Volume
49
Category
Article
ISSN
0044-8249

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## Abstract High‐pressure/high‐temperature conditions of 10 GPa and 1150 °C were used to synthesize the new rare‐earth oxoborates __α__‐(RE)~2~B~4~O~9~ (RE=Eu, Gd, Tb, Dy) in a Walker‐type multianvil apparatus. Single‐crystal X‐ray structure determination of __α__‐(RE)~2~B~4~O~9~ (RE=Eu, Gd, Tb) re