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High-Pressure Preparation, Crystal Structure, and Properties of α-Ln2B4O9 (Ln: Eu, Gd, Tb, Dy): Oxoborates Displaying a New Type of Structure with Edge-Sharing BO4 Tetrahedra.

✍ Scribed by Holger Emme; Hubert Huppertz

Publisher
John Wiley and Sons
Year
2003
Weight
80 KB
Volume
34
Category
Article
ISSN
0931-7597

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High-Pressure Preparation, Crystal Struc
High-Pressure Preparation, Crystal Structure, and Properties of α-(RE)2B4O9 (RE=Eu, Gd, Tb, Dy): Oxoborates Displaying a New Type of Structure with Edge-Sharing BO4 Tetrahedra
✍ Holger Emme; Hubert Huppertz 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB 👁 1 views

## Abstract High‐pressure/high‐temperature conditions of 10 GPa and 1150 °C were used to synthesize the new rare‐earth oxoborates __α__‐(RE)~2~B~4~O~9~ (RE=Eu, Gd, Tb, Dy) in a Walker‐type multianvil apparatus. Single‐crystal X‐ray structure determination of __α__‐(RE)~2~B~4~O~9~ (RE=Eu, Gd, Tb) re