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Multianvil High-Pressure Synthesis of Dy4B6O15: The First Oxoborate with Edge-Sharing BO4 Tetrahedra.

✍ Scribed by Hubert Huppertz; Benjamin von der Eltz


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract High‐pressure/high‐temperature conditions of 10 GPa and 1150 °C were used to synthesize the new rare‐earth oxoborates __α__‐(RE)~2~B~4~O~9~ (RE=Eu, Gd, Tb, Dy) in a Walker‐type multianvil apparatus. Single‐crystal X‐ray structure determination of __α__‐(RE)~2~B~4~O~9~ (RE=Eu, Gd, Tb) re

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Hydrate Borate. -Violet, air-and water-resistant crystals of the title compound are synthesized from a stoichiometric mixture of Co3O4 and H3BO3 (Walker-type multianvil apparatus, 6 GPa, 880 °C, 5 min). The new high--pressure phase is characterized by powder and single crystal XRD, IR, and Raman spe