ChemInform Abstract: Formation of Edge-Sharing BO4 Tetrahedra in the High-Pressure Borate HP—NiB2O4.
✍ Scribed by Johanna S. Knyrim; Felix Roessner; Stefanie Jakob; Dirk Johrendt; Isabel Kinski; Robert Glaum; Hubert Huppertz
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 18 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Hydrate Borate. -Violet, air-and water-resistant crystals of the title compound are synthesized from a stoichiometric mixture of Co3O4 and H3BO3 (Walker-type multianvil apparatus, 6 GPa, 880 °C, 5 min). The new high--pressure phase is characterized by powder and single crystal XRD, IR, and Raman spe
## Abstract For Abstract see ChemInform Abstract in Full Text.
Co3O4 and H3BO3 in a Walker-type multi-anvil apparatus (6 GPa, 880 °C (Fe), 950 °C (Co), 10 min) and characterized by single crystal XRD, IR, Raman, and UV/VIS spectroscopy. They crystallize in the orthorhombic space group Pmn21 with Z = 2. The structure contains corner-sharing BO 4 tetrahedra and d