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ChemInform Abstract: Stable Oxoborate with Edge-Sharing BO4 Tetrahedra Synthesized under Ambient Pressure.

โœ Scribed by Shifeng Jin; Gemei Cai; Wanyan Wang; Meng He; Shunchong Wang; Xiaolong Chen


Publisher
John Wiley and Sons
Year
2010
Weight
17 KB
Volume
41
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

KZnB~3~O~6~ is synthesized under ambient pressure from a stoichiometric mixture of K~2~CO~3~, ZnO, and H~3~BO~3~ (500 ยฐC for 12 h and annealing at 750 ยฐC for 24 h).


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Hydrate Borate. -Violet, air-and water-resistant crystals of the title compound are synthesized from a stoichiometric mixture of Co3O4 and H3BO3 (Walker-type multianvil apparatus, 6 GPa, 880 ยฐC, 5 min). The new high--pressure phase is characterized by powder and single crystal XRD, IR, and Raman spe