✦ LIBER ✦

Spirodienones via a thermal uncatalyzed [1,3]-oxygen-to-carbon migration

✍ Scribed by Gary W Morrow; Shaopeng Wang; John S Swenton

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 229 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(88)85184-0

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Uncatalyzed 1,3-acyl migration from carb

Uncatalyzed 1,3-acyl migration from carbon to nitrogen. Conversion of β-iminoketones to enamides

✍ David Y. Curtin; Jack E. Richman 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 205 KB

Uncatalyzed 1,3-acyl migrations to or from a carbon atom of an unsaturated triad system have been rarely observed and except in unusual circumstances have proceded only at elevated temperatures (2). A recent report (3) has described a C-to-N migration in the rearrangement of

A novel 1,3-migration of the trimethylsi

A novel 1,3-migration of the trimethylsilyl group from oxygen to carbon

✍ L. Duhamel; J. Gralak; B. Ngono 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 226 KB

ChemInform Abstract: “Constructive” Crea

ChemInform Abstract: “Constructive” Creation of a Bimetallic Center via 1,4-Migration of a Trimethylsilyl Group from Oxygen to Carbon.

✍ T. N. MITCHELL; M. SCHUETZE; F. GIESSELMANN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

Thermal 1,5-rearrangement of a silyl gro

Thermal 1,5-rearrangement of a silyl group from oxygen to carbon

✍ Gerard Anderson; Donald W. Cameron; Geoffrey I. Feutrill; Roger W. Read 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 134 KB

The 1,3-migration of phosphorus from oxy

The 1,3-migration of phosphorus from oxygen to carbon: A new synthesis of β-ketophosphonates from enol phosphates

✍ Gerald B Hammond; Theodora Calogeropoulou; David F Wiemer 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 197 KB

Enol phosphates, readfly prepared from ketone enolates and dfalkyl phosphorochlorfdate, can be converted to the analogous 6-ketophosphonates by treatment wfth strong base.

Reversible 1,4 migration of a silyl grou

Reversible 1,4 migration of a silyl group from oxygen to carbon: an unexpected route to α-trialkylsilyl ketoximes

✍ J. Mora; A. Costa 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 203 KB

## Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group. After protonation, the resulting a-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.