Uncatalyzed 1,3-acyl migration from carbon to nitrogen. Conversion of β-iminoketones to enamides
✍ Scribed by David Y. Curtin; Jack E. Richman
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 205 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Uncatalyzed 1,3-acyl migrations to or from a carbon atom of an unsaturated triad system have been rarely observed and except in unusual circumstances have proceded only at elevated temperatures (2). A recent report (3) has described a C-to-N migration in the rearrangement of
📜 SIMILAR VOLUMES
Enol phosphates, readfly prepared from ketone enolates and dfalkyl phosphorochlorfdate, can be converted to the analogous 6-ketophosphonates by treatment wfth strong base.
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