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The 1,3-migration of phosphorus from oxygen to carbon: A new synthesis of β-ketophosphonates from enol phosphates

✍ Scribed by Gerald B Hammond; Theodora Calogeropoulou; David F Wiemer

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 197 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)94248-5

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✦ Synopsis

Enol phosphates, readfly prepared from ketone enolates and dfalkyl phosphorochlorfdate, can be converted to the analogous 6-ketophosphonates by treatment wfth strong base.

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