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ChemInform Abstract: “Constructive” Creation of a Bimetallic Center via 1,4-Migration of a Trimethylsilyl Group from Oxygen to Carbon.

✍ Scribed by T. N. MITCHELL; M. SCHUETZE; F. GIESSELMANN


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of Wasabi
✍ S. SATO; H. OBARA; K. YUSA; K. SUDO; M. SANDO; H. KAGAYA; H. IJICHI; S. MATSUBA; 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

## Synthesis of Wasabidienone A via a Novel Acyl Rearrangement Reaction from Carbon to Oxygen. -The key step in the synthesis of the yellow pigment wasabidienone A (VII) is the rearrangement of an acyl group from carbon to the β-hydroxy oxygen of the cyclohexadienone (V). This novel type of react