ChemInform Abstract: Novel Intramolecular Electrophilic Rearrangement: Migration of Alkoxycarbonyl Group from Carbon Atom to an Anionic Nitrogen Center.

ChemInform Abstract: Novel [1,N]-Carbon

ChemInform Abstract: Novel [1,N]-Carbon to Carbon Rearrangement of an Ester Group via Organotitanium Intermediates Wherein the N Varies from 2 to 5. Full Scope and Limitation Leading Predominantly to the Rearrangement.

✍ T. YAMAZAKI; H. URABE; F. SATO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 43 KB 👁 2 views

Novel [1,N]-Carbon to Carbon Rearrangement of an Ester Group via Organotitanium Intermediates Wherein the N Varies from 2 to 5. Full Scope and Limitation Leading Predominantly to the Rearrangement. -Olefinic or acetylenic di-or tricarboxylates are shown to undergo a novel type of carbon-to-carbon r