✦ LIBER ✦

Specific enolates from α-aminoketones

✍ Scribed by Michael E. Garst; John N. Bonfiglio; David A. Grudoski; Jeffrey Marks

Book ID: 104242728
Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 221 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91571-0

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✦ Synopsis

Although the effects of the a-heteroatoms halogenl, sulfur2, and oxygen3 on ketone enolate formation have been documented, the effect of an a-nitrogen substituent on enolization does not appear to have been examined. We anticipate the use of enolates from a-aminoketones in alkaloid synthesis and wish to report results addressing the directionality of these enolates.

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