α-chloroacyltrimethylsilanes as α-trimethylsilylacyl equivalents. specific C-acylation of enolates
✍ Scribed by Isao Kuwajima; Kazuhisa Matsumoto
- Book ID
- 108384898
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 204 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A method for the preparation of a-azido-masked acyl cyanides as synthetic equivalents of N-protected-C-activated a-amino acids was developed using carbon-carbon bond formation between aldehydes and the Masked Acyl Cyanide Reagents, followed by sulfonylation and substitution by azide anion. This meth
The use of cis-aminoindanol as a chiral auxiliary for asymmetric synthesis of c~-amino acids is described. Alkylation of the chirally modified glycine enolate 2 with a number of alkyl halides in the presence of lithium chloride gave the corresponding alkylated product in 90 -99% diastereoselectivity