𝔖 Bobbio Scriptorium
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Oxidation of Cyclic α-Aminoketones.

✍ Scribed by Hans Moehrle; Christiane Rohn


Book ID
102007125
Publisher
John Wiley and Sons
Year
2007
Weight
28 KB
Volume
38
Category
Article
ISSN
0931-7597

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Specific enolates from α-aminoketones
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Although the effects of the a-heteroatoms halogenl, sulfur2, and oxygen3 on ketone enolate formation have been documented, the effect of an a-nitrogen substituent on enolization does not appear to have been examined. We anticipate the use of enolates from a-aminoketones in alkaloid synthesis and wis

A New Rearrangement of α-Aminoketones
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Zur Kenntnis der α-Aminoketone
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\N HZ X.CO CHa XC CH CHS C0.X HC CX Ich konnte zeigen I), daB wenigstens bei rrromatisch-alipbatiscben Aminoketonen zuniichst eine Kondensation der Aminbase und zwar zu einem Dihydropyrazin stattfindet, z. B. beim a-Aminoacetophenon gemiiB dem Schema TT -KT N HzC C.CsHs -7 Dip}ienyl-dihydropyrazin,