Solvothermal Synthesis and Crystal Structure of the New Layered Thioantimonate(III) [Ni(C4H13N3)2] 9Sb22S42×0.5H2O: Interconnection of the SbS3, SbS4, and SbS5 Primary Building Units Yielding the Very Large Sb30S30 Heteroring.
✍ Scribed by Ralph Straehler; Wolfgang Bensch
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =
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