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Solvothermal Synthesis and Crystal Structure of the New Layered Thioantimonate(III) [Ni(C4H13N3)2]9Sb22S42 · 0.5H2O: Interconnection of the SbS3, SbS4, and SbS5 Primary Building Units Yielding the Very Large Sb30S30 Heteroring

✍ Scribed by Ralph Stähler; Wolfgang Bensch


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
324 KB
Volume
628
Category
Article
ISSN
0372-7874

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Solvothermal Synthesis, Crystal Structur
✍ Ralph Stähler; Christian Näther; Wolfgang Bensch 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 342 KB 👁 2 views

The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =