โ Scribed by Masami Honshoh; Hitoshi Kanno; Toyotoshi Ueda
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Solutions of various concentrations of tetramethylammonium chloride and trimethylammonium chloride in liquid hydrogen chloride have been examined by Raman spectroscopy and the solvation number of Cl^โ^ anions in these solutions determined. It was found for solutions up to 3 mol I^โ1^ of
Raman OH stretching spectra were measured for glassy pure ethanol and LiCl,RCB,OH solutions (R = moles of C\*H,OH over moles of LiCl) . Resolved Raman peaks at = 3309 and ir 3373 cm-' grow with an increase in LiCl concentration. The ~3309 cm-' band is tentatively assigned to the OH stretching vibrat
Analgsis of ir~trsnwlvculnr contributions calculuicd from sclwtivc: T1 nwahurcmcnts for hydrosyl :~nd methyl protons of mc&mo: solutions of diaml::nctic XI~, provides cvidcncc of a negative salvation effect for I-. ClOi and CNS-ions. At Low conccntrarions the microdynamic behaviour of LIIC hydrosyl
Inl~nnt~es oi f-f bands of rhc rio'\* and Es+ chlonde Ilcohol sole~tes ha\c been m~crr~~xed For these sol~~rcr the Rz Judd-Of&r paramctcr r~lucs are sgmficantly hrgher compared IO the aquomns The mcrczc oi chs sz2 paramcrcr VAUCS IS in the order: Hz0 < CH@H C CzHSOH < nCjH,OH.
The significance of plots of hydration enthalpies u.s ionization potentials is questioned. Aqueous ionization enthalpies for transition-metal ions (crystal-field-corrected). and ionization potentials, are linearly related, but a hook sequence in similar plots for closed-shell species is remarked. Se