## Abstract The negative ion mass spectra of methanol, methanol‐__d__ and trideuteromethanol have been measured at 70 eV. Use of deuterated methanols has enabled the ion at __m__/__e__ 31 to be identified as CH~3~O^−^ and not CH~2~OH^−^. Isotope effects have been determined for H^−^ and D^−^ format
Negative solvation of diamagnetic ions in methanol
✍ Scribed by L. Latanowicz; Z. Paja̧k
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 387 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Analgsis of ir~trsnwlvculnr contributions calculuicd from sclwtivc: T1 nwahurcmcnts for hydrosyl :~nd methyl protons of mc&mo: solutions of diaml::nctic XI~, provides cvidcncc of a negative salvation effect for I-. ClOi and CNS-ions. At Low conccntrarions the microdynamic behaviour of LIIC hydrosyl group is strongly affected wh~rcas that of the ~ncthyl g,ruup appears to bc unchanged.
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