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The negative ion mass spectra of methanol and deuterated methanol

โœ Scribed by J. C. J. Thynne

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
176 KB
Volume
7
Category
Article
ISSN
1076-5174

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โœฆ Synopsis

Abstract

The negative ion mass spectra of methanol, methanolโ€d and trideuteromethanol have been measured at 70 eV. Use of deuterated methanols has enabled the ion at m/e 31 to be identified as CH~3~O^โˆ’^ and not CH~2~OH^โˆ’^. Isotope effects have been determined for H^โˆ’^ and D^โˆ’^ formation, and for OH^โˆ’^ and OD^โˆ’^ formation. It has been shown that OH^โˆ’^ formation occurs as a rearrangement reaction as well as by simple C๏ฃฟO bond fission.

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