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Intensity of ff bands of heavy lanthanide chloride alcohol solvates

✍ Scribed by B. Keller; K. Bukietyńska; B. Jeżowska-Trzebiatowska

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
437 KB
Volume
92
Category
Article
ISSN
0009-2614

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✦ Synopsis

Inl~nnt~es oi f-f bands of rhc rio'* and Es+ chlonde Ilcohol sole~tes ha\c been m~crr~~xed For these sol~~rcr the Rz Judd-Of&r paramctcr r~lucs are sgmficantly hrgher compared IO the aquomns The mcrczc oi chs sz2 paramcrcr VAUCS IS in the order: Hz0 < CH@H C CzHSOH < nCjH,OH.

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Absorption spectra of holmunn mtrate III MFA and DbfF have been measured III the range 8000-42000 cm-'. The TA parameters were evaluated from the expenmental oscillator strengths usmg the Judd equation For Ho(N03)3 m DbIF a conslderable mcrease m 72 was observed, suggestmg the existence of mner-sphe